PUBLICATION LIST
2024
Z. Sun, C. Ollier, A. Rancz, B. Thienpont, K. Grohe, L. Becker, A. Purea, F. Engelke, S. Wagner, J. Sturgis, T. Le Marchand, T. Polenova and G. Pintacuda. “Pushing the Boundaries of Resolution in Solid-State NMR of Biomolecules with 160 kHz MAS”, Chem Commun., under revision.
M. Bonaccorsi, T. Le Marchand, Z. Sun, C. Ollier, T. Schubeis and G. Pintacuda. “Probing protein backbone and side-chains motions through the simultaneous measurement of 1H-15N and 1H-13C dipolar couplings with fast-MAS NMR”, J. Phys. Chem. Lett., under revision.
J. Koppe, K. J. Sanders, T. C. Robinson, A. L. Lejeune, D. Proriol, S. Wegner, A. Purea, F. Engelke, R. J. Clément, C. P. Grey, A. J. Pell and G. Pintacuda. “Resolving Structures of Paramagnetic Systems in Chemistry and Materials Science by Solid-State NMR: the Revolving Power of Ultra-Fast MAS”, Angew. Chem. Int. Ed. Engl., 2024, 63, e202408704. In press.
J. Koppe , A. Yakimov , D. Gioffrè , M.-E. Usteri , T. Vosegaard , G. Pintacuda , A. Lesage , A. J. Pell , S. Mitchell , J. Pérez-Ramírez and C. Copéret. “Coordination environments of platinum single atom catalysts from NMR fingerprints”, Nature, under revision. Preprint available on Research Square at https://doi.org/10.21203/rs.3.rs-4793204/v1.
A. Ashuiev, F. Allouche, M. A. Islam, J. P. Carvalho, K. J. Sanders, M. P. Conley, D. Klose, G. Lapadula, M. Wörle, D. Baabe, M. D. Walter, A. J. Pell, C. Copéret, G. Jeschke, G. Pintacuda and R. A. Andersen. “Geometry and Electronic Structure of Yb(III)[CH(SiMe3)2]3 from EPR and solid-state NMR augmented by Computations”, Phys. Chem. Chem. Phys. 2024, 26, 8734-8747.
R. Kumar, T. Le Marchand, L. Adam, R. Bobrovs, G. Chen, J. Fridmanis, N. Kronqvist, H. Biverstål, K. Jaudzems, J. Johansson, G. Pintacuda and A. Abelein. “Identification of potential aggregation hotspots on Aβ42 fibrils blocked by the anti-amyloid chaperone-like BRICHOS domain”, Nature Comm. 2024, 15, 965.
S. Séjourné, A. Labrunie; C. Dalinot, D. Canevet, R. Geuchaichia, J. Bou Zeid, A. Benchohra, T. Cauchy, B. Arnaud, M. Allain, C. Chamignon, J. Viger-Gravel, G. Pintacuda, V. Carré, F. Aubriet, N. Vanthuyne, M. Sallé and S. Goeb. “Chiral Truxene-based Self-assembled Cages: Triple Interlocking and Supramolecular Chirogenesis”, Angew. Chem. Int. Ed. Engl. 2024, 63, e202400961.
2023
E. N. Bassey, I. D. Seymour, J. D. Bocarsly, D. Keen, G. Pintacuda and C. P. Grey “Structure and Dynamics in the Layered Mg-doped Sodium Manganate Battery Cathode, via Total Scattering, NMR, EPR and Ab Initio Calculations” Chem. Mater., 2023, in press.
T. Robinson, K. J. Sanders, A. J. Pell and G. Pintacuda. “Multidimensional Methods and Paramagnetic NMR”, in Two‐Dimensional (2D) NMR Methods, K. L. Ivanov, P. K. Madhu, G. Rajalakshmi eds., pages 415-434, Wiley, 2023.
2022
A. Simion, T. Schubeis, T. Le Marchand, M. Vasilescu, G. Pintacuda, A. Lesage and C. Filip. “Heteronuclear decoupling with rotor-synchronized phase-alternated cycles”, J. Chem. Phys. 2022, 157.
T. Le Marchand, T. Schubeis, M. Bonaccorsi, P. Paluch, D. Lalli, A. J. Pell, L. B. Andreas, K. Jaudzems, J. Stanek and G. Pintacuda. “1H-detected biomolecular NMR under fast magic-angle spinning”, Chem. Rev. 2022, 122, 9943-10018.
N. T. Johansen, M. Bonaccorsi, T. Bengtsen, A. H. Larsen, F. G. Tidemand, M. C. Pedersen, P. Huda, J. Berndtsson, T. Darwish, N. R. Yepuri, A. Martel, T. G. Pomorski, A. Bertarello, M. Sansom, M. Rapp, R. Crehuet, T. Schubeis, K. Lindorff-Larsen, G. Pintacuda and L. Arleth. “Mg2+-dependent conformational equilibria in CorA and an integrated view on transport regulation”, eLife 2022, 11, e71887.
L. Barret, T. Schubeis, V. Kugler, L. Guyot, G. Pintacuda and R. Wagner. “Production and Preparation of Isotopically Labeled Human Membrane Proteins in Pichia pastoris for Fast-MAS-NMR Analyses Fast-MAS-NMR analyses”, Methods Mol. Biol. 2022, 2550, 171-178.
S. Bahri, R. Silvers, B. Michael, K. Jaudzems, D. Lalli, G. Casano, O. Ouari, A. Lesage, G. Pintacuda, S. Linse and R. G. Griffin. “1H detection and dynamic nuclear polarization–enhanced NMR of Aβ1-42 fibrils”, Proc. Natl. Acad. Sci. USA 2022, 119, e2114413119.
2021
K. Jaudzems, A. Kirsteina, T. Schubeis, G. Casano, O. Ouari, J. Bogans, A. Kazaks, K. Tars, A. Lesage and G. Pintacuda. “Structural Analysis of an Antigen Chemically Coupled on Virus‐Like Particles in Vaccine Formulation”, Angew. Chem. Int. Ed. Engl. 2021, 60, 12847-12851.
A. Daskalov, D. Martinez, V. Coustou, N. El Mammeri, M. Berbon, L. B. Andreas, B. Bardiaux, J. Stanek, A. Noubhani, B. Kauffmann, J. S. Wall, G. Pintacuda, S. J. Saupe, B. Habenstein and A. Loquet. “Structural and molecular basis of cross-seeding barriers in amyloids”, Proc. Natl. Acad. Sci. USA 2021, 118, e2014085118.
M. Bonaccorsi, T. Le Marchand and G. Pintacuda. “Protein structural dynamics by magic-angle spinning NMR”, Curr. Opin. Struct. biol. 2021, 70, 34-43.
J. Blahut, A. L. Lejeune, S. Ehrling, I. Senkovska, S. Kaskel, F. M. Wisser and G. Pintacuda. “Monitoring Dynamics, Structure, and Magnetism of Switchable Metal–Organic Frameworks via 1H‐Detected MAS NMR”, Angew. Chem. Int. Ed. Engl. 2021, 60, 21778-21783.
J. Blahut, L. Benda, A. L. Lejeune, K. J. Sanders, B. Burcher, E. Jeanneau, D. Proriol, L. Catita, P.-A. R. Breuil, A.-A. Quoineaud, A. Pell and G. Pintacuda. “Proton-detected fast-magic-angle spinning NMR of paramagnetic inorganic solids”, RSC Adv. 2021, 11, 29870-29876.
B. Aubry, R. Canterel, M. Lansalot, E. Bourgeat‐Lami, A. Airoudj, B. Graff, C. Dietlin, F. Morlet‐Savary, J. Blahut, L. Benda, G. Pintacuda, E. Lacôte and J. Lalevée. “Development of a Borane–(Meth) acrylate Photo‐Click Reaction”, Angew. Chem. Int. Ed. Engl. 2021, 60, 17037-17044.
T. Schubeis, J. Stanek and G. Pintacuda. “Backbone assignment of crystalline E. coli maltose binding protein”, Biomol. NMR. Assing. 2021, 15, 317-322.
A. Ashuiev, M. Humbert, S. Norsic, J. Blahut, D. Gajan, K. Searles, D. Klose, A. Lesage, G. Pintacuda, J. Raynaud, V. Monteil, C. Copéret and G. Jeschke. “Spectroscopic Signature and Structure of the Active Sites in Ziegler–Natta Polymerization Catalysts Revealed by Electron Paramagnetic Resonance”, J. Am. Chem. Soc. 2021, 143, 9791-9797.
2020
K. Xue, R. Sarkar, D. Lalli, B. Koch, G. Pintacuda, Z. Tosner and B. Reif. “Impact of magnetic field strength on resolution and sensitivity of proton resonances in biological solids”, J. Phys. Chem. C 2020, 124, 22631-22637.
T. Schubeis, T. S. Schwarzer, T. Le Marchand, J. Stanek, K. T. Movellan, K. Castiglione, G. Pintacuda and L. B. Andreas. “Resonance assignment of the outer membrane protein AlkL in lipid bilayers by proton-detected solid-state NMR”, Biomol. NMR. Assing. 2020, 14, 295-300.
A. Bertarello, L. Benda, K. J. Sanders, A. J. Pell, M. J. Knight, V. Pelmenschikov, L. Gonnelli, I. C. Felli, M. Kaupp, L. Emsley, R. Pierattelli and G. Pintacuda. “Picometer resolution structure of the coordination sphere in the metal-binding site in a metalloprotein by NMR”, J. Am. Chem. Soc. 2020, 142, 16757-16765. (spotlight article)
M. Bonaccorsi, M. J. Knight, T. Le Marchand, H. R. Dannatt, T. Schubeis, L. Salmon, I. C. Felli, L. Emsley, R. Pierattelli and G. Pintacuda. “Multimodal response to copper binding in superoxide dismutase dynamics”, J. Am. Chem. Soc. 2020, 142, 19660-19667.
T. Schubeis, T. Le Marchand, C. Daday, W. Kopec, K. Tekwani Movellan, J. Stanek, T. S. Schwarzer, K. Castiglione, B. L. de Groot and G. Pintacuda. “A β-barrel for oil transport through lipid membranes: Dynamic NMR structures of AlkL”, Proc. Natl. Acad. Sci. USA 2020, 117, 21014-21021.
J. Blahut, L. Benda, J. Kotek, G. Pintacuda and P. Hermann. “Paramagnetic Cobalt (II) Complexes with Cyclam Derivatives: Toward 19F MRI Contrast Agents”, Inorg. Chem. 2020, 59, 10071-10082.
B. M. Sala, T. Le Marchand, G. Pintacuda, C. Camilloni, A. Natalello and S. Ricagno. “Conformational stability and dynamics in crystals recapitulate protein behavior in solution”, Biophys. J. 2020, 119, 978-988.
J. Stanek, T. Schubeis, P. Paluch, P. Guntert, L. B. Andreas and G. Pintacuda. “Automated backbone NMR resonance assignment of large proteins using redundant linking from a single simultaneous acquisition”, J. Am. Chem. Soc. 2020, 142, 5793-5799. (spotlight article)
H. W. Orton, J. Stanek, T. Schubeis, D. Foucaudeau, C. Ollier, A. W. Draney, T. Le Marchand, D. Cala‐De Paepe, I. C. Felli, R. Pierattelli and G. Pintacuda. “Protein NMR Resonance Assignment without Spectral Analysis: 5D SOlid‐State Automated Projection SpectroscopY (SO‐APSY)”, Angew. Chem. Int. Ed. Engl. 2020, 59, 2380-2384.
2019
K. Xue, R. Sarkar, Z. Tosner, D. Lalli, C. Motz, B. Koch, G. Pintacuda and B. Reif. “MAS dependent sensitivity of different isotopomers in selectively methyl protonated protein samples in solid state NMR”, J. Biomol. NMR 2019, 73, 625-631.
T. Polenova, A. Goldbourt and G. Pintacuda. “Structure and dynamics of biomolecular assemblies by solid-state NMR”, J. Struct. Biol. 2019, 207, 103-103. (Editorial)
A. J. Pell, G. Pintacuda and C. P. Grey. “Paramagnetic NMR in solution and the solid state”, Prog. Nucl. Magn. Reson. Spectrosc. 2019, 111, 1-271.
E. E. Najbauer, K. T. Movellan, T. Schubeis, T. Schwarzer, K. Castiglione, K. Giller, G. Pintacuda, S. Becker and L. B. Andreas. “Probing Membrane Protein Insertion into Lipid Bilayers by Solid‐State NMR”, ChemPhysChem 2019, 20, 302-310.
K. Jaudzems, T. Polenova, G. Pintacuda, H. Oschkinat and A. Lesage. “DNP NMR of biomolecular assemblies”, J. Struct. Biol. 2019, 206, 90-98.
R. Gupta, H. Zhang, M. Lu, G. Hou, M. Caporini, M. Rosay, W. Maas, J. Struppe, J. Ahn, I.-J. L. Byeon, H. Oschkinat, K. Jaudzems, E. Barbet-Massin, L. Emsley, G. Pintacuda, A. Lesage, A. M. Gronenborn and T. Polenova. “Dynamic nuclear polarization magic-angle spinning nuclear magnetic resonance combined with molecular dynamics simulations permits detection of order and disorder in viral assemblies”, J. Phys. Chem. B 2019, 123, 5048-5058.
2018
T. Schubeis, T. Le Marchand, L. B. Andreas and G. Pintacuda. “1H magic-angle spinning NMR evolves as a powerful new tool for membrane proteins”, J. Magn. Reson. 2018, 287, 140-152. (invited perspective article)
K. J. Sanders, A. J. Pell, S. Wegner, C. P. Grey and G. Pintacuda. “Broadband MAS NMR spectroscopy in the low-power limit”, Chem. Phys. Lett. 2018, 697, 29-37.
A. Marchanka, J. Stanek, G. Pintacuda and T. Carlomagno. “Rapid access to RNA resonances by proton-detected solid-state NMR at> 100 kHz MAS”, Chem. Commun. 2018, 54, 8972-8975.
T. L. Marchand, M. de Rosa, N. Salvi, B. M. Sala, L. B. Andreas, E. Barbet-Massin, P. Sormanni, A. Barbiroli, R. Porcari, C. S. Mota, D. De Sanctis, M. Bolognesi, L. Emsley, V. Bellotti, M. Blackledge, C. Camilloni, G. Pintacuda and S. Ricagno. “Conformational dynamics in crystals reveal the molecular bases for D76N beta-2 microglobulin aggregation propensity”, Nat. Commun. 2018, 9, 1658.
A. Loquet, N. El Mammeri, J. Stanek, M. Berbon, B. Bardiaux, G. Pintacuda and B. Habenstein. “3D structure determination of amyloid fibrils using solid-state NMR spectroscopy”, Methods 2018, 138, 26-38.
A. Kryshtafovych, R. Albrecht, A. Basle, P. Bule, A. T. Caputo, A. L. Carvalho, K. L. Chao, R. Diskin, K. Fidelis, C. M. Fontes, F. Fredslund, H. J. Gilbert, C. W. Goulding, M. D. Hartmann, C. S. Hayes, O. Herzberg, J. C. Hill, A. Joachimiak, G.-W. Kohring, R. I. Koning, L. Lo Leggio, M. Mangiagalli, K. Michalska, J. Moult, S. Najmudin, M. Nardini, V. Nardone, D. Ndeh, T.-H. Nguyen, G. Pintacuda, S. Postel, M. J. van Raaij, P. Roversi, A. Shimon, A. K. Singh, E. J. Sundberg, K. Tars, N. Zitzmann and T. Schwede. “Target highlights from the first post‐PSI CASP experiment (CASP12, May–August 2016)”, Proteins 2018, 86, 27-50.
K. Jaudzems, A. Bertarello, S. R. Chaudhari, A. Pica, D. Cala‐De Paepe, E. Barbet‐Massin, A. J. Pell, I. Akopjana, S. Kotelovica, D. Gajan, O. Ouari, K. Tars, G. Pintacuda and A. Lesage. “Dynamic Nuclear Polarization‐Enhanced Biomolecular NMR Spectroscopy at High Magnetic Field with Fast Magic‐Angle Spinning”, Angew. Chem. Int. Ed. Engl. 2018, 57, 7458-7462.
C. Ferrara, S. Ferrari, M. Bini, D. Capsoni, G. Pintacuda and P. Mustarelli. “To which extent is paramagnetic solid-state NMR able to address polymorphism in complex transition-metal oxides?”, J. Phys. Chem. Lett. 2018, 9, 6072-6076.
A. Bertarello and G. Pintacuda. “Solid-state NMR of paramagnetic proteins”, in Paramagnetism in Experimental Biomolecular NMR, C. Luchinat, G. Parigi, E. Ravera eds. Pages 163-188, Royal Society of Chemistry, London, 2018.
2017
J. Struppe, C. M. Quinn, M. Lu, M. Wang, G. Hou, X. Lu, J. Kraus, L. B. Andreas, J. Stanek, D. Lalli, A. Lesage, G. Pintacuda, W. Maas, A. M. Gronenborn and T. Polenova. “Expanding the horizons for structural analysis of fully protonated protein assemblies by NMR spectroscopy at MAS frequencies above 100 kHz”, Solid State Nucl. Magn. Reson. 2017, 87, 117-125.
O. Saurel, I. Iordanov, G. Nars, P. Demange, T. Le Marchand, L. B. Andreas, G. Pintacuda and A. Milon. “Local and global dynamics in Klebsiella pneumoniae outer membrane protein a in lipid bilayers probed at atomic resolution”, J. Am. Chem. Soc. 2017, 139, 1590-1597.
J. S. Retel, A. J. Nieuwkoop, M. Hiller, V. A. Higman, E. Barbet-Massin, J. Stanek, L. B. Andreas, W. T. Franks, B.-J. Van Rossum, K. R. Vinothkumar, L. Handel, G. G. de Palma, B. Bardiaux, G. Pintacuda, L. Emsley, W. Kühlbrandt and H. Oschkinat. “Structure of outer membrane protein G in lipid bilayers”, Nat. Commun. 2017, 8, 2073.
A. J. Pell, K. J. Sanders, S. Wegner, G. Pintacuda and C. P. Grey. “Low-power broadband solid-state MAS NMR of 14N”, J. Chem. Phys. 2017, 146.
M. Otikovs, M. Andersson, Q. Jia, K. Nordling, Q. Meng, L. B. Andreas, G. Pintacuda, J. Johansson, A. Rising and K. Jaudzems. “Degree of biomimicry of artificial spider silk spinning assessed by NMR spectroscopy”, Angew. Chem. 2017, 129, 12745-12749.
D. Lalli, M. N. Idso, L. B. Andreas, S. Hussain, N. Baxter, S. Han, B. F. Chmelka and G. Pintacuda. “Proton-based structural analysis of a heptahelical transmembrane protein in lipid bilayers”, J. Am. Chem. Soc. 2017, 139, 13006-13012. (cover article and spotlight article)
M. G. Jain, D. Lalli, J. Stanek, C. Gowda, S. Prakash, T. S. Schwarzer, T. Schubeis, K. Castiglione, L. B. Andreas, P. Madhu, G. Pintacuda and A. V. “Selective 1H–1H distance restraints in fully protonated proteins by very fast magic-angle spinning solid-state NMR”, J. Phys. Chem. Lett. 2017, 8, 2399-2405.
N. C. George, J. Brgoch, A. J. Pell, C. Cozzan, A. Jaffe, G. Dantelle, A. Llobet, G. Pintacuda, R. Seshadri and B. F. Chmelka. “Correlating local compositions and structures with the macroscopic optical properties of Ce3+-doped CaSc2O4, an efficient green-emitting phosphor”, Chem. Mater. 2017, 29, 3538-3546.
D. Cala-De Paepe, J. Stanek, K. Jaudzems, K. Tars, L. B. Andreas and G. Pintacuda. “Is protein deuteration beneficial for proton detected solid-state NMR at and above 100 kHz magic-angle spinning?”, Solid State Nucl. Magn. Reson. 2017, 87, 126-136.
B. Burcher, K. J. Sanders, L. Benda, G. Pintacuda, E. Jeanneau, A. A. Danopoulos, P. Braunstein, H. Olivier-Bourbigou and P.-A. R. Breuil. “Straightforward access to stable, 16-valence-electron phosphine-stabilized Fe0 Olefin complexes and their reactivity”, Organometallics 2017, 36, 605-613.
A. Bertarello, T. Schubeis, C. Fuccio, E. Ravera, M. Fragai, G. Parigi, L. Emsley, G. Pintacuda and C. Luchinat. “Paramagnetic properties of a crystalline iron–sulfur protein by magic-angle spinning NMR spectroscopy”, Inorg. Chem. 2017, 56, 6624-6629.
2016
J. Stanek, L. B. Andreas, K. Jaudzems, D. Cala, D. Lalli, A. Bertarello, T. Schubeis, I. Akopjana, S. Kotelovica, K. Tars, A. Pica, S. Leone, D. Picone, Z.-Q. Xu, N. E. Dixon, D. Martinez, M. Berbon, N. El Mammeri, A. Noubhani, S. Saupe, B. Habenstein, A. Loquet, G. Pintacuda, “Backbone and side-chain proton NMR assignment in fully protonated proteins: microcrystals, sedimented assemblies, and amyloid fibrils”, Angew. Chem. Int. Ed. Engl. 2016, 55, 15504-15509; Angew. Chem. 2016, 128, 15730-15735. (frontispice article)
M. Shishovs, J. Rumnieks, C. Diebolder, K. Jaudzems, L. B. Andreas, J. Stanek, A. Kazaks, S. Kotelovica, I. Akopjana, G. Pintacuda, R. I. Koning, K. Tars, “Structure of AP205 coat protein reveals circular permutation in ssRNA bacteriophages”, J. Mol. Biol., 2016, 428, 4267-4279. (cover article)
V. D'Anna, S. Norsic, D. Gajan, K. Sanders, A. J. Pell, A. Lesage, V. Monteil, C. Copéret, G. Pintacuda, P. Sautet, “Structural Characterization of the EtOH-TiCl4-MgCl2 Ziegler-Natta Pre-Catalyst”, J. Phys. Chem. C, 2016, 120, 18075-18087.
L. B. Andreas, K. Jaudzems, J. Stanek, D. Lalli, A. Bertarello, T. Le Marchand, D. Cala-De Paepe, S. Kotelovica, I. Akopjana, B. Knott, S. Wegner, F. Engelke, A. Lesage, L. Emsley, K. Tars, T. Herrmann, and G. Pintacuda “Structure of fully protonated proteins by proton-detected magic-angle spinning NMR”, Proc. Natl. Acad. Sci. USA, 2016, 113, 9187-9192.
H. R. W. Dannatt, M. Felletti, S. Jehle, Y. Wang, L. Emsley, N. E. Dixon, A. Lesage and G. Pintacuda “Weak and Transient Protein Interactions Determined by Solid-State NMR” Angew. Chem. Int. Ed. Engl. 2016, 55, 6638–6641.
R. Gupta, M. Lu, G. Hou, M. Caporini, M. Rosay, W. Maas, J. Struppe, C. Suiter, J. Ahn, I.-J. Byeon, W. T. Franks, M. Orwick-Rydmark, A. Bertarello, H. Oschkinat, A. Lesage, G. Pintacuda, A. Gronenborn and T. Polenova, "Dynamic Nuclear Polarization Enhanced MAS NMR for Structural Analysis of HIV-1 Protein Assemblies" J. Phys. Chem. B 2016, 120, 329-39.
2015
R. Sarkar, D. Rodriguez Camargo, G. Pintacuda, and B. Reif, "Restoring Resolution in Biological Solid-State NMR under Conditions of Off-Magic-Angle Spinning" J. Phys. Chem. Lett. 2015, 6, 5040-5044.
L. B. Andreas, M. Reese, M. T. Eddy, V. Gelev, Q. Z. Ni, E. A. Miller, L. Emsley, G. Pintacuda, J. J. Chou, and R. G. Griffin, “Structure and Mechanism of the Influenza A M218–60 Dimer of Dimers” J. Am. Chem. Soc. 2015, 137, 14877-14886.
L. B. Andreas, J. Stanek, T. Le Marchand, A. Bertarello, D. C.-D. Paepe, D. Lalli, M. Krejcikova, C. Doyen, C. Oester, B. Knott, S. Wegner, F. Engelke, I. C. Felli, R. Pierattelli, N. E. Dixon, L. Emsley, T. Herrmann, and G. Pintacuda, “Protein residue linking in a single spectrum for magic-angle spinning NMR assignment” J. Biomol. NMR 2015, 62, 253-261.
M. T. Eddy, Y.Su, R. Silvers, L. B. Andreas, L. Clark, G. Wagner, G. Pintacuda, L. Emsley, and R. G. Griffin “Lipid−Bilayer-Bound Conformation of an Integral Membrane Beta Barrel Protein by Multidimensional MAS NMR”, J. Biomol. NMR, 2015, 61, 299-310.
A. J. Nieuwkoop, W. T. Franks, Ü. Akbey, K. Rehbein, A. Diehl, L. Emsley, G. Pintacuda and H. Oschkinat “Comparing the Sensitivity and Resolution of Spectra of a Deuterated Protein at 40 and 60 kHz Magic−Angle Spinning”, J. Biomol. NMR, 2015, 61, 161-171.
L. B. Andreas, T. Le Marchand, K. Jaudzems and G. Pintacuda “High resolution proton−detected NMR of proteins at very fast MAS”, J. Magn. Reson., 2015, 253, 36-49.
A. J. Pell and G. Pintacuda “Broadband solid−state MAS NMR of paramagnetic systems”, Progr. Nucl. Magn. Reson. Spectrosc., 2015, 84-85, 33-72.
2014
E. Barbet-Massin, A. J. Pell, J. S. Retel, L. B. Andreas, K. Jaudzems, W. T. Franks, A. J. Nieuwkoop, M. Hiller, V. Higman, P. Guerry, A. Bertarello, M. J. Knight, M. Felletti, T. Le Marchand, S. Kotelovica, I. Akopjana, K. Tars, M. Stoppini, V. Bellotti, M. Bolognesi, S. Ricagno, J. J. Chou, R. G. Griffin, H. Oschkinat, A. Lesage, L. Emsley, T. Herrmann and G. Pintacuda “Rapid proton-detected NMR assignment for proteins with fast magic angle spinning”, J. Am. Chem. Soc., 2014, 136, 12489-12497.
R. Linser, B. Bardiaux, L. B. Andreas, S. G. Hyberts, V. K. Morris, G. Pintacuda, M. Sunde, A. H. Kwan, and G. Wagner “Solid-State NMR Structure Determination from Diagonal-Compensated Proton-Proton Restraints”, J. Am. Chem. Soc., 2014, 136, 11002-11010.
E. Barbet-Massin, M. Felletti, R. Schneider, S. Jehle, G. Communie, N. Martinez, M. Ringkjøbing Jensen, R. W.H. Ruigrok, L. Emsley A. Lesage, M. Blackledge and G. Pintacuda “Insights into the structure and dynamics of measles virus nucleocapsids by 1H-detected solid-state NMR“, Biophys. J., 2014, 107, 941-946.
C. Ferrara, C. Tealdi, P. Mustarelli, M. Hoelzel, A. J. Pell, and G. Pintacuda “Melilite LaSrGa3−xAlxO7 Series: A Combined Solid-State NMR and Neutron Diffraction Study” J. Phys. Chem. C, 2014, 118, 15036-15043.
F. C. Strobridge, D. S. Middlemiss, A. J. Pell, M. Leskes, R. J. Clement, F. Pourpoint, Z. Lu, J. V. Hanna, G. Pintacuda, L. Emsley, A. Samoson, and C. P. Grey. “Characterising local environments in high energy density Li-ion battery cathodes: a combined NMR and first principles study of LiFexCo1-xPO4”, J. Mat. Chem. A 2014, 2, 11948-11957.
J. Xu, H. Lee Dae, R. J. Clément, X. Yu, M. Leskes, A. J. Pell, G. Pintacuda, X.-Q. Yang, C. P. Grey and Y. S. Meng ”Identifying the Critical Role of Li Substitution in P2-Nax[LiyNizMn1-y-z]O2 (0 < x, y, z < 1) Intercalation Cathode Materials for High-Energy Na-Ion Batteries”, Chem. Mat., 2014, 26, 1260-1269.
2013
N. George, A. J. Pell, G. Dantelle, K. Page, A. Llobet, M. Balasubramanian, G. Pintacuda, B. Chmelka, R. Seshadri, "Local environments of dilute activator ions in the solid-state lighting phosphor” Chem. Mat. 2013, 25, 3979-3995.
M. Bini, S. Ferrari, C. Ferrara, M. C. Mozzati, D. Capsoni, A. J. Pell, G. Pintacuda, P. Canton and P. Mustarelli “Polymorphism and magnetic properties of Li2MSiO4 (M = Fe, Mn) cathode materials”, Sci. Reports, 2013, 3, 3452.
C. Ferrara, C. Tealdi, A. Pedone, M. C. Menziani, A. J. Rossini, G. Pintacuda and P. Mustarelli, “Local Versus Average Structure in LaSrAl 3O 7: a NMR and DFT Investigation”, J. Phys. Chem. C 2013, 117, 23451–23458.
E. Barbet-Massin, A. J. Pell, K. Jaudzems, W. T. Franks, J. S. Retel, S. Kotelovica, I. Akopjana, K. Tars, L. Emsley, H. Oschkinat, A. Lesage and G. Pintacuda "Out-and-back 13C-13C scalar transfers in protein resonance assignment by proton-detected solid-state NMR under ultra-fast MAS" J. Biomol. NMR, 2013, 56, 379-386.
M. J. Knight, I. C. Felli, R. Pierattelli, L. Emsley and G. Pintacuda “Magic angle spinning NMR of paramagnetic proteins“, Acc. Chem. Res. 2013, 46, 2108-16.
E. Barbet-Massin, A. J. Pell, M. J. Knight, A. L. Webber, I. C. Felli, R. Pierattelli, L. Emsley, A. Lesage and G. Pintacuda “13C-detected through-bond correlation experiments for protein resonance assignment by ultra-fast MAS solid-state NMR” ChemPhysChem 2013, 14, 3131-7.
A. J. Pell, R. J. Clément, C. P. Grey, L. Emsley and G. Pintacuda “Frequency-stepped acquisition in nuclear magnetic resonance spectroscopy under magic angle spinning” J. Chem. Phys. 2013, 138, 114201.
2012
R. J. Clément, A. J. Pell, D. S. Middlemiss, F. C. Strobridge, J. K. Miller, S. M. Whittingham, L. Emsley, C. P. Grey, and G. Pintacuda “Spin-transfer pathways in paramagnetic lithium transition metal phosphates from combined broadband isotropic solid-state MAS NMR spectroscopy and DFT calculations“, J. Am. Chem. Soc. 2012, 134, 17178-17185.
A. Marchetti, S. Jehle, M. Felletti, M. J. Knight, Y. Wang, Z.-Q. Xu, A. Y. Park, G. Otting, A. Lesage, L. Emsley, N. E. Dixon and G. Pintacuda “Backbone NMR chemical shift assignment of fully protonated solid proteins by 1H detection and ultra-fast magic-angle spinning“, Angew. Chem. Int. Ed. Engl. 2012, 51, 10756-10759.
M. J. Knight, I. C. Felli, R. Pierattelli, I. Bertini, T. Herrmann, L. Emsley and G. Pintacuda “Rapid measurement of pseudocontact shifts in metalloproteins by proton-detected solid-state NMR spectroscopy“, J. Am. Chem. Soc. 2012, 134, 14730-14733.
M. J. Knight, A. J. Pell, I. Bertini, I. C. Felli, L. Gonnelli, R. Pierattelli, T. Herrmann, L. Emsley and G. Pintacuda “Structure and backbone dynamics of a microcrystalline metalloprotein by solid-state NMR“, Proc. Natl. Acad. Sci. USA 2012, 109, 11095-11100.
M. J. Knight and G. Pintacuda “Paramagnetic Systems in Biochemistry: Solid-State NMR Studies”, in “Encyclopedia of Magnetic Resonance”, R. Harris and R. Wasylishen eds., John Wiley & Sons, Chichester, England, 2012.
E. Barbet-Massin and G. Pintacuda “Biomolecular solid-state NMR - Basics”. NMR of biomolecules: Towards Mechanistic Systems Biology, I. Bertini, K. McGreevy and G. Parigi (eds.) John Wiley & Sons Ltd. Chichester, England, 2012.
G. Pintacuda and G. Kervern “Paramagnetic solid−state NMR spectroscopy“, in H. Heise and S. Matthews, eds., Topics in Current Chemistry “Modern NMR methodology”, Springer, Heidelberg, 2012 (in press).
A. L. Webber, A. J. Pell, E. Barbet-Massin, M. J. Knight, I. Bertini, I. C. Felli, R. Pierattelli, L. Emsley, A. Lesage and G. Pintacuda “ Combination of DQ and ZQ coherences for sensitive through-bond NMR correlation experiments in biosolids under ultra-fast MAS“, ChemPhysChem, 2012, 13, 2405–2411.
2011
M. J. Knight, A. L. Webber, A. J. Pell, P. Guerry, E. Barbet-Massin, I. Bertini, I. C. Felli, L. Gonnelli, R. Pierattelli, L. Emsley, A. Lesage, T. Herrmann and G. Pintacuda “Fast Resonance Assignment and Fold Determination of Human Superoxide Dismutase by High-Resolution Proton-Detected Solid-State MAS NMR Spectroscopy”, Angew. Chem. Int. Ed., 2011, 50, 11697-11701.
A. J. Pell, G. Pintacuda, L. Emsley “Single crystal NMR in spinning powders”, J. Chem. Phys., 2011, 135, 144201.
B. Graham, C. T. Loh, J. Swarbrick, P. Ung, J. Shin, H. Yagi, X. Jia, S. Chhabra, N. Barlow, G. Pintacuda, T. Huber and G. Otting ”A DOTA-amide lanthanide tag for reliable generation of pseudocontact shifts in protein NMR spectra”, Bioconj. Chem., 2011, 22, 2118-25.
I. Bertini, L. Emsley, I. C. Felli, S. Laage, A. Lesage, J. Lewandowski, A. Marchetti, R. Pierattelli and G. Pintacuda “High-Resolution and Sensitivity Through-Bond Correlations in Ultra-Fast Magic Angle Spinning (MAS) Solid-State NMR”, Chem. Sci., 2011, 2, 345-348.
2010
A. J. Pell, G. Kervern, M. Deschamps, D. Massiot, L. Emsley, P. J. Grandinetti and G. Pintacuda “Broadband inversion for MAS NMR with single-sideband-selective adiabatic pulses (S3APs)”, J. Chem. Phys., 2010, 134, 024117.
L. Di Bari, G. Pintacuda and P. Salvadori “Stereoselection in the binding of LnDOTA to γ−cyclodextrin: a Near IR Circular Dichroism study”, Chirality, 2010, 22, 11-16.
I. Bertini, L. Emsley, C. Luchinat, M. Lelli, Y. Mao and G. Pintacuda “Ultra-Fast MAS High Field Solid-State NMR Permits Extensive 13C and 1H Detection in Paramagnetic Metalloproteins”, J. Am. Chem. Soc., 2010, 132, 5558-5559.
E. Barbet-Massin, S. Ricagno, J. Lewandowski, S. Giorgetti, V. Bellotti, M. Bolognesi, L. Emsley and G. Pintacuda “Fibrillar vs Crystalline Full-length Beta-2-microglobulin Studied by High-Resolution Solid-State NMR Spectroscopy”, J. Am. Chem. Soc., 2010, 132, 5556-5557.
J. Estephane, E. Groppo, J. Vitillo, A. Damin, D. Gianolio, C. Lamberti, S. Bordiga, A. E. Quadrelli, J.−M. Basset, G. Kervern, L. Emsley, G. Pintacuda and A. Zecchina, “A Multi−Technique Approach to Spin−Flips for Cp2Cr(II) Chemistry in Confined State”, J. Phys. Chem. C, 2010, 114, 4451–4458.
2009
A. Böckmann, C. Gardiennet, R. Verel, A. Hunkeler, A. Loquet, G. Pintacuda, L. Emsley, B. H. Meier and A. Lesage “Characterization of different water pools in solid-state NMR protein samples”, J. Biomol. NMR 2009, 45, 319-327.
S. Laage, A. Lesage, L. Emsley, I. Bertini, I. C. Felli, R. Pierattelli and G. Pintacuda "Transverse-Dephasing Optimized Homonuclear J-Decoupling in Solid-State NMR Spectroscopy of Uniformly 13C-Labeled Proteins", J. Am. Chem. Soc. 2009, 131, 10816-10817.
G. Kervern, A. D'Aleo, O. Maury, L. Emsley and G. Pintacuda "Crystal structure determination of powdered paramagnetic lanthanide complexes by proton NMR" Angew. Chem. Int. Ed. Engl., 2009, 48, 3082-3086.
S. Laage, J. R. Sachleben, S. Steuernagel, R. Pierattelli, G. Pintacuda, and L. Emsley, "Fast acquisition of multidimensional NMR experiments enabled by ultra-fast MAS" J. Magn. Reson., 2009, 196, 133-141.
2008
S. Laage, A. Marchetti, J. Sein, R. Pierattelli, H. J. Sass, S. Grzesiek, A. Lesage, G. Pintacuda and L. Emsley, "Band-Selective 1H-13C Cross-Polarization in Ultra-Fast Biomolecular MAS Solid-State NMR", J. Am. Chem. Soc., 2008, 130, 17216–17217.
M. Deschamps, G. Kervern, D. Massiot, G. Pintacuda, L. Emsley and P. J. Grandinetti "Superadiabaticity in magnetic resonance" J. Chem. Phys., 2008, 119, 204110.
A. Lesage, C. Gardiennet, A. Loquet, R. Verel, G. Pintacuda, L. Emsley, B. H. Meier, and A. Böckmann, " Polarization Transfer over the Water–Protein Interface in Solids" Angew. Chem. Int. Ed. Engl., 2008, 47, 5851-5854 ; "Polarisationstransfer über die Wasser−Protein−Grenzfläche im Festkörper", Angew. Chem. 2008, 120, 5935-5938.
2007
G. Kervern, S. Steuernagel, F. Engelke, G. Pintacuda and L. Emsley "Absence of Curie relaxation in paramagnetic solids yields long 1H coherence lifetimes", J. Am. Chem. Soc., 2007, 129, 14118-14119.
C. J. Pickard, E. Salager, G. Pintacuda, B. Elena and L. Emsley "Resolving structures from powders by NMR crystallography using combined proton spin diffusion and plane wave DFT calculations", J. Am. Chem. Soc., 2007, 129, 8932-8933.
G. Kervern, G. Pintacuda and L. Emsley “Fast adiabatic pulses for solid-state NMR of paramagnetic systems”, Chem. Phys. Lett., 2007, 435, 157-162.
G. Pintacuda, M. John, X.-C. Su and G. Otting "NMR structure determination of protein-ligand complexes by lanthanide labeling", Acc. Chem. Res., 2007, 40, 206-212.
2006
G. Pintacuda, N. Giraud, R. Pierattelli, A. Böckmann, I. Bertini and L. Emsley "Solid-State NMR of a Paramagnetic Protein: Assignment and Study of the Human Dimeric Oxidized Zn(II)-Cu(II) Superoxide Dismutase (SOD)", Angew. Chem. Int. Ed. Engl., 2006, 46, 1079-1082.
N. Giraud, J. Sein, G. Pintacuda, A. Böckmann, A. Lesage, M. Blackledge and L. Emsley "Observation of Heteronuclear Overhauser Effect Confirms the 15N-1H Dipolar Relaxation Mechanism in a Crystalline Protein", J. Am. Chem. Soc., 2006, 128, 12398-12399.
G. Kervern, G. Pintacuda, Y. Zhang, E. Oldfield, C. Roukoss, E. Kuhn, E. Herdtweck, J.-M. Basset, S. Cadars, A. Lesage, C. Coperet and L. Emsley “Solid-state NMR of a paramagnetic DIAD-Fe(II) catalyst: sensitivity, resolution enhancement, and structure-based assignment”, J. Am. Chem. Soc., 2006, 128, 13545-13552.
M. John, G. Pintacuda, A.-Y. Park, N. E. Dixon and G. Otting "Structure determination of protein-ligand complexes by transferred paramagnetic shifts", J. Am. Chem. Soc., 2006, 128, 12910-12916.
B. Elena, G. Pintacuda, N. Mifsud and L. Emsley “Molecular structure determination in powders by NMR crystallography from proton spin diffusion”, J. Am. Chem. Soc., 2006, 128, 9555-9560.
M. A. Keniry, A.-Y. Park, E. A. Owen, S. M. Hamdan, G. Pintacuda, G. Otting and N. E. Dixon “Structure of the theta subunit of Escherichia coli DNA polymerase III in complex with the epsilon subunit”, J. Bacteriol., 2006, 188, 4464-4473.
G. Pintacuda, M. A. Keniry, E. Owen, A.-Y. Park, N. E. Dixon and G. Otting “Lanthanide labeling offers fast NMR approach to 3D structure determinations of protein-protein complexes”, J. Am. Chem. Soc., 2006, 128, 3696-3702.
C. Schmitz, M. John, A.-Y. Park, N. E. Dixon, G. Otting, G. Pintacuda and T. Huber “Efficient chi-tensor determination and NH assignment of paramagnetic proteins”, J. Biomol. NMR, 2006, 35, 79-87.
G. Pintacuda, T. Huber, M. A. Keniry, A.-Y. Park, N. E. Dixon and G. Otting “Fast assignments of 15N-HSQC spectra of proteins by paramagnetic labelling”, in Handbook of modern magnetic resonance, G. Webb ed.; pages 1245-1251; Kluwer Academic Publisher, Amsterdam, 2006.
2005
M. John, A.-Y. Park, G. Pintacuda, N. E. Dixon and G. Otting “Weak alignment of paramagnetic proteins warrants correction for residual CSA effects in measurements of pseudocontact shifts”, J. Am. Chem. Soc., 2005, 127, 17190-17191.
M. Lelli, G. Pintacuda, A. Cuzzola and L. Di Bari “Monitoring proton dissociation and solution conformation of chiral ytterbium complexes with near-IR CD”, Chirality, 2005, 17, 201-211.
A. J. Oakley, K. V. Loscha, P. M. Schaeffer, E. Liepinsh, G. Pintacuda, M.C. J. Wilce, G. Otting and N. E. Dixon “Crystal and solution structure of the helicase-binding domain of Escherichia Coli primase”, J. Biol. Chem., 2005, 280, 11495-11504.
2004
G. Pintacuda, A. Kaikkonen and G. Otting “Modulation of the distance dependence of paramagnetic relaxation enhancements by DSA×CSA cross-correlation”, J. Magn. Reson. 2004, 171, 233-243.
G. Pintacuda, A. Moshref, A. Leonchiks, A. Sharipo and G. Otting “Site-specific labelling with a metal chelator for protein-structure refinement”, J. Biomol. NMR, 2004, 29, 351-361.
G. Pintacuda, M. A. Keniry, T. Huber, A.-Y. Park, N. E. Dixon and G. Otting “Fast structure-based assignment of 15N-HSQC of paramagnetic proteins”, J. Am. Chem. Soc., 2004, 126, 2963-2970.
G. Pintacuda “NMR and NIR-CD studies of lanthanide complexes in solution”, Ph. D. Thesis, published by the Scuola Normale Superiore. Pubblicazioni della Classe di Scienze, collana “Tesi”, Pisa (Italy), 2004.
2003
E. Liepinsh, L. Banjay, G. Pintacuda, M. Trexler, L. Patthy and G. Otting “NMR structure of the netrin-like domain of human type I procollagen C-proteinase enhancer-1 defines structural consensus of NTR domains and assesses potential proteinase inhibitory activity and ligand binding”, J. Biol. Chem., 2003, 278, 25982-25989.
G. Pintacuda, K. Hohenthanner, N. Mueller and G. Otting “Angular dependence of dipole-dipole-Curie-spin cross-correlation effects in high-spin and low-spin paramagnetic myoglobin”, J. Biomol. NMR, 2003, 27, 115-132.
L. Di Bari, M. Lelli, G. Pintacuda, G. Pescitelli, F. Marchetti and P. Salvadori “Solution geometry and structural rearrangement in ytterbium heterobimetallic catalysts”, J. Am. Chem. Soc., 2003, 125, 5549-5558.
2002
G. Pintacuda and G. Otting “Identification of protein surfaces by NMR measurements by a paramagnetic lanthanide chelate”, J. Am. Chem. Soc., 2002, 124, 372-373.
L. Di Bari, G. Pintacuda, S. Ripoli, P. Salvadori “Structure of metal adducts of anthracyclines probed by absorption, circular dichroism and paramagnetic NMR”, Magn. Reson. Chem., 2002, 40, 396-405.
L. Di Bari, M. Lelli, G. Pintacuda, P. Salvadori “Yb(fod)3 in the spectroscopic determination of the configuration of chiral diols: a survey of the lanthanide diketonate method”, Chirality, 2002, 14, 265-273.
2000
L. Di Bari, G. Pintacuda, P. Salvadori, R. S. Dickins, D. Parker “Effect of Axial Ligation on the Magnetic and Electronic Properties of Lanthanide Complexes of Octadentate Ligands”, J. Am. Chem. Soc., 2000, 122, 9257-9264.
L. Di Bari, G. Pintacuda, P. Salvadori “Stereochemistry and Near-Infrared Circular Dichroism of a Chiral Yb Complex”, J. Am. Chem. Soc., 2000, 122, 5557-5562.
L. Di Bari, G. Pintacuda, P. Salvadori “Solution Equilibria in YbDOTMA, a Chiral Analogue of One of the Most Successful Contrast Agents for MRI, GdDOTA”, Eur. J. Inor. Chem., 2000, 75-82.